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Interval 1 in emulsion polymerisation

Term · Chemistry · MLC-T-CHM-005995

The first period of a batch emulsion polymerization, during which new polymer particles are formed, for example by radicals entering monomer-swollen surfactant micelles, while monomer droplets serve as a reservoir. Particle number and polymerization rate both rise, and the interval ends when no new particles form, typically at a few percent conversion. Interval 2 follows, with constant particle number and monomer droplets still present.

Table 1. Record
IdentifierMLC-T-CHM-005995
FieldChemistry
SubjectPolymer
ReferencesPAC, 2011, 83, 2229. 'Terminology of polymers and polymerization processes in dispersed systems (IUPAC Recommendations 2011)' on page 2246 (https://doi.org/10.1351/PAC-REC-10-06-03)
See alsoAb initio emulsion polymerisation; Batch emulsion polymerisation
Record as JSON
{
  "id": "MLC-T-CHM-005995",
  "term": "Interval 1 in emulsion polymerisation",
  "field": "Chemistry",
  "definition": "The first period of a batch emulsion polymerization, during which new polymer particles are formed, for example by radicals entering monomer-swollen surfactant micelles, while monomer droplets serve as a reservoir. Particle number and polymerization rate both rise, and the interval ends when no new particles form, typically at a few percent conversion. Interval 2 follows, with constant particle number and monomer droplets still present.",
  "subject": "Polymer",
  "see_also": [
    "ab initio emulsion polymerisation",
    "batch emulsion polymerisation"
  ],
  "references": [
    "PAC, 2011, 83, 2229. 'Terminology of polymers and polymerization processes in dispersed systems (IUPAC Recommendations 2011)' on page 2246 (https://doi.org/10.1351/PAC-REC-10-06-03)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/interval-1-in-emulsion-polymerisation/"
}

Record 6,363 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.