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Limiting diffusion current

Term · Chemistry · MLC-T-CHM-006599

The maximum current observed in an electrochemical system that is solely controlled by the rate at which an electroactive species diffuses from the bulk solution to the electrode surface. This current becomes constant when the concentration of the electroactive species at the electrode surface approaches zero. It is directly proportional to the concentration of the electroactive species in the bulk solution.

Table 1. Record
IdentifierMLC-T-CHM-006599
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1495 (https://doi.org/10.1351/pac198557101491)
See alsoApplied potential; Diffusion current
Record as JSON
{
  "id": "MLC-T-CHM-006599",
  "term": "Limiting diffusion current",
  "field": "Chemistry",
  "definition": "The maximum current observed in an electrochemical system that is solely controlled by the rate at which an electroactive species diffuses from the bulk solution to the electrode surface. This current becomes constant when the concentration of the electroactive species at the electrode surface approaches zero. It is directly proportional to the concentration of the electroactive species in the bulk solution.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "applied potential",
    "diffusion current"
  ],
  "references": [
    "PAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1495 (https://doi.org/10.1351/pac198557101491)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/limiting-diffusion-current/"
}

Record 6,994 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.