MLchartDataset catalogue

Half-wave potential

Term · Chemistry · MLC-T-CHM-005076

The potential at which the current in a polarographic or voltammetric experiment reaches exactly half of its limiting current value. This potential is characteristic of the electroactive species undergoing reduction or oxidation at the electrode surface. It is independent of the concentration of the electroactive species and is measured against a reference electrode.

Table 1. Record
IdentifierMLC-T-CHM-005076
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1502 (https://doi.org/10.1351/pac198557101491)
See alsoIndicator electrode; Limiting current; Residual current
Record as JSON
{
  "id": "MLC-T-CHM-005076",
  "term": "Half-wave potential",
  "field": "Chemistry",
  "definition": "The potential at which the current in a polarographic or voltammetric experiment reaches exactly half of its limiting current value. This potential is characteristic of the electroactive species undergoing reduction or oxidation at the electrode surface. It is independent of the concentration of the electroactive species and is measured against a reference electrode.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "indicator electrode",
    "limiting current",
    "residual current"
  ],
  "references": [
    "PAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1502 (https://doi.org/10.1351/pac198557101491)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/half-wave-potential/"
}

Record 5,379 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.