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Half-peak potential

Term · Chemistry · MLC-T-CHM-005074

The potential at which the current in a voltammetric peak, such as in cyclic voltammetry, reaches half of its maximum value. This parameter is often used to characterize the reversibility of an electrochemical reaction and can provide information about the electron transfer kinetics. For a reversible system, the half-peak potential is related to the formal potential of the redox couple.

Table 1. Record
IdentifierMLC-T-CHM-005074
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1502 (https://doi.org/10.1351/pac198557101491)
See alsoIndicator electrode; Peak current; Residual current
Record as JSON
{
  "id": "MLC-T-CHM-005074",
  "term": "Half-peak potential",
  "field": "Chemistry",
  "definition": "The potential at which the current in a voltammetric peak, such as in cyclic voltammetry, reaches half of its maximum value. This parameter is often used to characterize the reversibility of an electrochemical reaction and can provide information about the electron transfer kinetics. For a reversible system, the half-peak potential is related to the formal potential of the redox couple.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "indicator electrode",
    "peak current",
    "residual current"
  ],
  "references": [
    "PAC, 1985, 57, 1491. 'Recommended terms, symbols, and definitions for electroanalytical chemistry (Recommendations 1985)' on page 1502 (https://doi.org/10.1351/pac198557101491)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/half-peak-potential/"
}

Record 5,377 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.