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Levich equation

Term · Chemistry · MLC-T-CHM-006543

An equation that describes the limiting current at a rotating disc electrode under steady-state conditions, relating it to the electrode rotation rate, the concentration of the electroactive species, and its diffusion coefficient. It is a fundamental equation in electroanalytical chemistry for studying mass transport phenomena. The limiting current is directly proportional to the square root of the rotation rate.

Table 1. Record
IdentifierMLC-T-CHM-006543
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 674 (https://doi.org/10.1515/pac-2018-0109)
See alsoElectrode surface area; Electron number of an electrochemical reaction; Hydrodynamic voltammetry; Rotating disc electrode
Record as JSON
{
  "id": "MLC-T-CHM-006543",
  "term": "Levich equation",
  "field": "Chemistry",
  "definition": "An equation that describes the limiting current at a rotating disc electrode under steady-state conditions, relating it to the electrode rotation rate, the concentration of the electroactive species, and its diffusion coefficient. It is a fundamental equation in electroanalytical chemistry for studying mass transport phenomena. The limiting current is directly proportional to the square root of the rotation rate.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "electrode surface area",
    "electron number of an electrochemical reaction",
    "hydrodynamic voltammetry",
    "rotating disc electrode"
  ],
  "references": [
    "PAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 674 (https://doi.org/10.1515/pac-2018-0109)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/levich-equation/"
}

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