MLchartDataset catalogue

Nozzle-skimmer dissociation

Term · Chemistry · MLC-T-CHM-008088

The fragmentation of ions that occurs in the region between the atmospheric pressure ionization source nozzle and the skimmer in a mass spectrometer. This dissociation is induced by collisions with residual gas molecules as ions expand into the vacuum, often facilitated by a potential difference between the nozzle and skimmer. It is a form of in-source collision-induced dissociation.

Table 1. Record
IdentifierMLC-T-CHM-008088
FieldChemistry
SubjectAnalytical Chemistry
Synonymsin-source collision-induced dissociation
ReferencesPAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1572 (https://doi.org/10.1351/PAC-REC-06-04-06)
See alsoAtmospheric pressure chemical ionization; Nozzle-skimmer voltage
Record as JSON
{
  "id": "MLC-T-CHM-008088",
  "term": "Nozzle-skimmer dissociation",
  "field": "Chemistry",
  "definition": "The fragmentation of ions that occurs in the region between the atmospheric pressure ionization source nozzle and the skimmer in a mass spectrometer. This dissociation is induced by collisions with residual gas molecules as ions expand into the vacuum, often facilitated by a potential difference between the nozzle and skimmer. It is a form of in-source collision-induced dissociation.",
  "synonyms": [
    "in-source collision-induced dissociation"
  ],
  "subject": "Analytical Chemistry",
  "see_also": [
    "atmospheric pressure chemical ionization",
    "nozzle-skimmer voltage"
  ],
  "references": [
    "PAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1572 (https://doi.org/10.1351/PAC-REC-06-04-06)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/nozzle-skimmer-dissociation/"
}

Record 8,586 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.