MLchartDataset catalogue

Peroxy acids

Term · Chemistry · MLC-T-CHM-008680

Compounds in which the acidic hydroxyl group of an acid, usually a carboxylic acid, is exchanged for a hydroperoxy group, -OOH, as in peracetic acid, CH3C(=O)OOH. Peroxycarboxylic acids such as meta-chloroperoxybenzoic acid are strong oxygen-transfer reagents that epoxidize alkenes and convert ketones to esters in the Baeyer-Villiger oxidation.

Table 1. Record
IdentifierMLC-T-CHM-008680
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
Synonymsper acids; peracids
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1356 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-008680",
  "term": "Peroxy acids",
  "field": "Chemistry",
  "definition": "Compounds in which the acidic hydroxyl group of an acid, usually a carboxylic acid, is exchanged for a hydroperoxy group, -OOH, as in peracetic acid, CH3C(=O)OOH. Peroxycarboxylic acids such as meta-chloroperoxybenzoic acid are strong oxygen-transfer reagents that epoxidize alkenes and convert ketones to esters in the Baeyer-Villiger oxidation.",
  "synonyms": [
    "per acids",
    "peracids"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1356 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/peroxy-acids/"
}

Record 9,217 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.