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Relative hardness

Term · Chemistry · MLC-T-CHM-010143

The absolute hardness of a molecule minus that of a matching reference structure, where absolute hardness is half the gap between the ionization energy and the electron affinity. The quantity tracks the resonance stabilization of cyclic conjugated molecules and is used as an index of aromaticity in theoretical organic chemistry.

Table 1. Record
IdentifierMLC-T-CHM-010143
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1960 (https://doi.org/10.1351/pac199971101919)
See alsoAromaticity; Resonance
Record as JSON
{
  "id": "MLC-T-CHM-010143",
  "term": "Relative hardness",
  "field": "Chemistry",
  "definition": "The absolute hardness of a molecule minus that of a matching reference structure, where absolute hardness is half the gap between the ionization energy and the electron affinity. The quantity tracks the resonance stabilization of cyclic conjugated molecules and is used as an index of aromaticity in theoretical organic chemistry.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "aromaticity",
    "resonance"
  ],
  "references": [
    "PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1960 (https://doi.org/10.1351/pac199971101919)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/relative-hardness/"
}

Record 10,785 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.