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Retrograde solubility

Term · Chemistry · MLC-T-CHM-010304

A phenomenon where the solubility of a solute in a solvent decreases as the temperature increases, contrary to the more common behavior of increasing solubility with temperature. This behavior is often observed in gas-liquid systems or in certain polymer solutions. It is a key consideration in processes such as supercritical fluid extraction.

Table 1. Record
IdentifierMLC-T-CHM-010304
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2008, 80, 233. 'Glossary of terms related to solubility (IUPAC Recommendations 2008)' on page 261 (https://doi.org/10.1351/pac200880020233)
See alsoTernary diagram
Record as JSON
{
  "id": "MLC-T-CHM-010304",
  "term": "Retrograde solubility",
  "field": "Chemistry",
  "definition": "A phenomenon where the solubility of a solute in a solvent decreases as the temperature increases, contrary to the more common behavior of increasing solubility with temperature. This behavior is often observed in gas-liquid systems or in certain polymer solutions. It is a key consideration in processes such as supercritical fluid extraction.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "ternary diagram"
  ],
  "references": [
    "PAC, 2008, 80, 233. 'Glossary of terms related to solubility (IUPAC Recommendations 2008)' on page 261 (https://doi.org/10.1351/pac200880020233)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/retrograde-solubility/"
}

Record 10,952 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.