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Sampled DC polarography

Term · Chemistry · MLC-T-CHM-010501

A variant of direct current (DC) polarography where the current is measured only for a brief period at the end of the drop life of a dropping mercury electrode. This technique minimizes the contribution of capacitive current, which can obscure the faradaic current. It offers improved sensitivity and detection limits compared to conventional DC polarography.

Table 1. Record
IdentifierMLC-T-CHM-010501
FieldChemistry
SubjectAnalytical Chemistry
SynonymsTAST polarography
ReferencesPAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 678 (https://doi.org/10.1515/pac-2018-0109)
See alsoDC polarography; Current sampling
Record as JSON
{
  "id": "MLC-T-CHM-010501",
  "term": "Sampled DC polarography",
  "field": "Chemistry",
  "definition": "A variant of direct current (DC) polarography where the current is measured only for a brief period at the end of the drop life of a dropping mercury electrode. This technique minimizes the contribution of capacitive current, which can obscure the faradaic current. It offers improved sensitivity and detection limits compared to conventional DC polarography.",
  "synonyms": [
    "TAST polarography"
  ],
  "subject": "Analytical Chemistry",
  "see_also": [
    "DC polarography",
    "current sampling"
  ],
  "references": [
    "PAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 678 (https://doi.org/10.1515/pac-2018-0109)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sampled-dc-polarography/"
}

Record 11,170 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.