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Spin decoupling

Term · Chemistry · MLC-T-CHM-011200

A technique in nuclear magnetic resonance (NMR) spectroscopy where the spin-spin coupling between specific nuclei is eliminated by applying a strong radiofrequency field at the resonance frequency of one of the coupled nuclei. This simplifies the NMR spectrum by collapsing multiplets into singlets. It is widely used to assign signals and determine molecular structure.

Table 1. Record
IdentifierMLC-T-CHM-011200
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 705 (https://doi.org/10.1515/pac-2019-0203)
See alsoHeteronuclear decoupling; Homonuclear decoupling; Nuclear magnetic resonance spectroscopy
Record as JSON
{
  "id": "MLC-T-CHM-011200",
  "term": "Spin decoupling",
  "field": "Chemistry",
  "definition": "A technique in nuclear magnetic resonance (NMR) spectroscopy where the spin-spin coupling between specific nuclei is eliminated by applying a strong radiofrequency field at the resonance frequency of one of the coupled nuclei. This simplifies the NMR spectrum by collapsing multiplets into singlets. It is widely used to assign signals and determine molecular structure.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "heteronuclear decoupling",
    "homonuclear decoupling",
    "nuclear magnetic resonance spectroscopy"
  ],
  "references": [
    "PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 705 (https://doi.org/10.1515/pac-2019-0203)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/spin-decoupling/"
}

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