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Sulfenes

Term · Chemistry · MLC-T-CHM-011548

Highly reactive, transient organic compounds containing a sulfur atom double-bonded to a carbon atom and also double-bonded to an oxygen atom, with the general formula R2C=SO2. They are analogous to ketenes but with a sulfur dioxide group. Sulfenes are typically generated in situ and undergo rapid cycloaddition reactions.

Table 1. Record
IdentifierMLC-T-CHM-011548
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1368 (https://doi.org/10.1351/pac199567081307)
See alsoThioaldehydes; Thioketones
Record as JSON
{
  "id": "MLC-T-CHM-011548",
  "term": "Sulfenes",
  "field": "Chemistry",
  "definition": "Highly reactive, transient organic compounds containing a sulfur atom double-bonded to a carbon atom and also double-bonded to an oxygen atom, with the general formula R2C=SO2. They are analogous to ketenes but with a sulfur dioxide group. Sulfenes are typically generated in situ and undergo rapid cycloaddition reactions.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "thioaldehydes",
    "thioketones"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1368 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sulfenes/"
}

Record 12,308 of 13,678 in Chemistry terminology (MLC-0109). Request the full dataset.