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Sulfenic acids

Term · Chemistry · MLC-T-CHM-011549

Organosulfur compounds of the formula RSOH, with a hydroxyl group on divalent sulfur, the lowest oxidation level in the series of sulfenic, sulfinic and sulfonic acids. Most are too reactive to isolate, because two molecules condense with loss of water to form a thiosulfinate, RS(O)SR, so they appear as intermediates in thiol oxidation. Cysteine sulfenic acid is a reversible modification of protein thiols.

Table 1. Record
IdentifierMLC-T-CHM-011549
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1368 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-011549",
  "term": "Sulfenic acids",
  "field": "Chemistry",
  "definition": "Organosulfur compounds of the formula RSOH, with a hydroxyl group on divalent sulfur, the lowest oxidation level in the series of sulfenic, sulfinic and sulfonic acids. Most are too reactive to isolate, because two molecules condense with loss of water to form a thiosulfinate, RS(O)SR, so they appear as intermediates in thiol oxidation. Cysteine sulfenic acid is a reversible modification of protein thiols.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1368 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sulfenic-acids/"
}

Record 12,307 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.