MLchartDataset catalogue

Transient species

Term · Chemistry · MLC-T-CHM-012226

A short-lived reaction intermediate, such as a radical, carbene, carbocation or excited state, whose lifetime is too short for it to be isolated or observed by ordinary methods. What counts as transient depends on the experimental time scale and detection technique, so the same species can be transient in one experiment and persistent in another. Flash photolysis and pulse radiolysis detect transients with lifetimes from nanoseconds to milliseconds.

Table 1. Record
IdentifierMLC-T-CHM-012226
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
Synonymstransient chemical species
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1174 (https://doi.org/10.1351/pac199466051077)
See alsoIntermediate; Persistent; Unstable
Record as JSON
{
  "id": "MLC-T-CHM-012226",
  "term": "Transient species",
  "field": "Chemistry",
  "definition": "A short-lived reaction intermediate, such as a radical, carbene, carbocation or excited state, whose lifetime is too short for it to be isolated or observed by ordinary methods. What counts as transient depends on the experimental time scale and detection technique, so the same species can be transient in one experiment and persistent in another. Flash photolysis and pulse radiolysis detect transients with lifetimes from nanoseconds to milliseconds.",
  "synonyms": [
    "transient chemical species"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "intermediate",
    "persistent",
    "unstable"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1174 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/transient-species/"
}

Record 13,035 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.