Z₅₀
Term · Chemistry · MLC-T-CHM-012790
A measure of the fatigue resistance of a photochromic compound, given as the number of colouring and bleaching cycles after which the absorbance of the coloured form at a chosen wavelength has fallen to half its initial value. A larger Z50 means a more durable photochromic system. Diarylethenes are known for particularly high values, surviving many thousands of cycles, whereas many spiropyrans fatigue after far fewer.
| Identifier | MLC-T-CHM-012790 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 441 (https://doi.org/10.1351/pac200779030293) |
| See also | Absorbance; Wavelength |
Record as JSON
{
"id": "MLC-T-CHM-012790",
"term": "Z₅₀",
"field": "Chemistry",
"definition": "A measure of the fatigue resistance of a photochromic compound, given as the number of colouring and bleaching cycles after which the absorbance of the coloured form at a chosen wavelength has fallen to half its initial value. A larger Z50 means a more durable photochromic system. Diarylethenes are known for particularly high values, surviving many thousands of cycles, whereas many spiropyrans fatigue after far fewer.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"absorbance",
"wavelength"
],
"references": [
"PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 441 (https://doi.org/10.1351/pac200779030293)"
],
"url": "https://mlchart.com/terminology/chemistry/z50/"
}
Record 13,638 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.