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Acyclic diene metathesis polymerisation

Term · Chemistry · MLC-T-CHM-000212

A type of step-growth polymerization where acyclic diene monomers react via olefin metathesis to form a polymer and a small molecule byproduct, usually ethene. This reaction is catalyzed by transition metal complexes, such as those based on ruthenium or molybdenum. It is a powerful method for synthesizing unsaturated polymers with controlled microstructures.

Table 1. Record
IdentifierMLC-T-CHM-000212
FieldChemistry
SubjectPolymer
ReferencesPAC, 2008, 80, 2163. 'Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)' on page 2165 (https://doi.org/10.1351/pac200880102163)
Record as JSON
{
  "id": "MLC-T-CHM-000212",
  "term": "Acyclic diene metathesis polymerisation",
  "field": "Chemistry",
  "definition": "A type of step-growth polymerization where acyclic diene monomers react via olefin metathesis to form a polymer and a small molecule byproduct, usually ethene. This reaction is catalyzed by transition metal complexes, such as those based on ruthenium or molybdenum. It is a powerful method for synthesizing unsaturated polymers with controlled microstructures.",
  "subject": "Polymer",
  "references": [
    "PAC, 2008, 80, 2163. 'Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)' on page 2165 (https://doi.org/10.1351/pac200880102163)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/acyclic-diene-metathesis-polymerisation/"
}

Record 220 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.