MLchartDataset catalogue

Anhydro bases

Term · Chemistry · MLC-T-CHM-000606

Neutral compounds made from an iminium hydroxide, for instance a quaternary heterocyclic salt with a methyl group at the 2-position, when the hydroxide ion removes a proton from a position conjugated to the cationic C=N unit and water is lost. The product is an enamine-like methylene base, for example from 1,2-dimethylpyridinium or 1,2-dimethylquinolinium. Anhydro bases are strongly basic and take up a proton to regenerate the iminium cation.

Table 1. Record
IdentifierMLC-T-CHM-000606
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1317 (https://doi.org/10.1351/pac199567081307)
See alsoPseudo bases
Record as JSON
{
  "id": "MLC-T-CHM-000606",
  "term": "Anhydro bases",
  "field": "Chemistry",
  "definition": "Neutral compounds made from an iminium hydroxide, for instance a quaternary heterocyclic salt with a methyl group at the 2-position, when the hydroxide ion removes a proton from a position conjugated to the cationic C=N unit and water is lost. The product is an enamine-like methylene base, for example from 1,2-dimethylpyridinium or 1,2-dimethylquinolinium. Anhydro bases are strongly basic and take up a proton to regenerate the iminium cation.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "pseudo bases"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1317 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/anhydro-bases/"
}

Record 648 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.