MLchartDataset catalogue

Eclipsed

Term · Chemistry · MLC-T-CHM-003544

A conformation in which substituents on adjacent atoms are directly aligned with each other when viewed along the bond connecting those atoms. This arrangement typically represents a higher energy state due to steric hindrance and torsional strain. In ethane, the eclipsed conformation has a dihedral angle of 0 degrees between hydrogen atoms.

Table 1. Record
IdentifierMLC-T-CHM-003544
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2206 (https://doi.org/10.1351/pac199668122193)
See alsoBisecting conformation; Eclipsing strain; Torsion angle
Record as JSON
{
  "id": "MLC-T-CHM-003544",
  "term": "Eclipsed",
  "field": "Chemistry",
  "definition": "A conformation in which substituents on adjacent atoms are directly aligned with each other when viewed along the bond connecting those atoms. This arrangement typically represents a higher energy state due to steric hindrance and torsional strain. In ethane, the eclipsed conformation has a dihedral angle of 0 degrees between hydrogen atoms.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "bisecting conformation",
    "eclipsing strain",
    "torsion angle"
  ],
  "references": [
    "PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2206 (https://doi.org/10.1351/pac199668122193)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/eclipsed/"
}

Record 3,764 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.