Electron attachment
Term · Chemistry · MLC-T-CHM-003706
A process in which a free electron joins an atom, molecule, or ion, giving a species of more negative charge. It may be radiative, with a photon carrying off the excess energy, dissociative, with the molecule breaking into a fragment anion and a neutral piece, or three-body, with a third particle absorbing the excess energy. Dissociative attachment can occur even when the parent molecule has a negative electron affinity, as in the formation of chloride ion from chloromethane.
| Identifier | MLC-T-CHM-003706 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| References | PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1547 (https://doi.org/10.1351/pac199163101541); PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1109 (https://doi.org/10.1351/pac199466051077) |
| See also | Attachment; Molecular entity; Oxidation; Reduction |
Record as JSON
{
"id": "MLC-T-CHM-003706",
"term": "Electron attachment",
"field": "Chemistry",
"definition": "A process in which a free electron joins an atom, molecule, or ion, giving a species of more negative charge. It may be radiative, with a photon carrying off the excess energy, dissociative, with the molecule breaking into a fragment anion and a neutral piece, or three-body, with a third particle absorbing the excess energy. Dissociative attachment can occur even when the parent molecule has a negative electron affinity, as in the formation of chloride ion from chloromethane.",
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"attachment",
"molecular entity",
"oxidation",
"reduction"
],
"references": [
"PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1547 (https://doi.org/10.1351/pac199163101541)",
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1109 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/electron-attachment/"
}
Record 3,931 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.