Attachment
Term · Chemistry · MLC-T-CHM-000925
A transformation in which a substrate is converted into a larger molecular entity by forming exactly one two-center bond to another entity, with no other change in the substrate's connectivity. An example is carbon monoxide combining with a carbenium ion R+ to give the acylium ion RCO+. It differs from addition, in which a reagent forms two new bonds to an unsaturated substrate.
| Identifier | MLC-T-CHM-000925 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1086 (https://doi.org/10.1351/pac199466051077) |
| See also | Adduct; Bond; Carbenium ion; Cation; Colligation; Connectivity; Cycloaddition; Electron attachment; Molecular entity; Substrate; Transformation |
Record as JSON
{
"id": "MLC-T-CHM-000925",
"term": "Attachment",
"field": "Chemistry",
"definition": "A transformation in which a substrate is converted into a larger molecular entity by forming exactly one two-center bond to another entity, with no other change in the substrate's connectivity. An example is carbon monoxide combining with a carbenium ion R+ to give the acylium ion RCO+. It differs from addition, in which a reagent forms two new bonds to an unsaturated substrate.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"adduct",
"bond",
"carbenium ion",
"cation",
"colligation",
"connectivity",
"cycloaddition",
"electron attachment",
"molecular entity",
"substrate",
"transformation"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1086 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/attachment/"
}
Record 996 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.