Enolates
Term · Chemistry · MLC-T-CHM-003940
Anions derived from the deprotonation of an enolizable carbonyl compound, such as a ketone or aldehyde, at the alpha-carbon. These species are highly reactive nucleophiles and serve as key intermediates in many carbon-carbon bond-forming reactions. The negative charge is delocalized between the alpha-carbon and the oxygen atom, making them ambident nucleophiles.
| Identifier | MLC-T-CHM-003940 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1334 (https://doi.org/10.1351/pac199567081307) |
| See also | Aldehydes; Enols; Ketones |
Record as JSON
{
"id": "MLC-T-CHM-003940",
"term": "Enolates",
"field": "Chemistry",
"definition": "Anions derived from the deprotonation of an enolizable carbonyl compound, such as a ketone or aldehyde, at the alpha-carbon. These species are highly reactive nucleophiles and serve as key intermediates in many carbon-carbon bond-forming reactions. The negative charge is delocalized between the alpha-carbon and the oxygen atom, making them ambident nucleophiles.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"aldehydes",
"enols",
"ketones"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1334 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/enolates/"
}
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