MLchartDataset catalogue

Halonium ions

Term · Chemistry · MLC-T-CHM-005084

Cations of the form R2X+, in which a positively charged halogen atom (bromonium, chloronium, fluoronium or iodonium) is bonded to two carbon groups, either in an open chain, as in diaryliodonium salts, or in a ring. The three-membered cyclic type is called a halirenium ion and forms as an intermediate when halogens add to alkenes, giving anti addition products.

Table 1. Record
IdentifierMLC-T-CHM-005084
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1339 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-005084",
  "term": "Halonium ions",
  "field": "Chemistry",
  "definition": "Cations of the form R2X+, in which a positively charged halogen atom (bromonium, chloronium, fluoronium or iodonium) is bonded to two carbon groups, either in an open chain, as in diaryliodonium salts, or in a ring. The three-membered cyclic type is called a halirenium ion and forms as an intermediate when halogens add to alkenes, giving anti addition products.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1339 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/halonium-ions/"
}

Record 5,387 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.