Munchnones
Term · Chemistry · MLC-T-CHM-007696
A class of five-membered mesoionic heterocyclic compounds, formally known as 1,3-oxazolium-5-olates. Their structure cannot be represented by a single covalent Lewis formula and is instead depicted as a resonance hybrid of several canonical forms, showing delocalized positive and negative charges. Munchnones are highly reactive and are commonly used as 1,3-dipoles in cycloaddition reactions to synthesize other heterocyclic systems, such as pyrroles.
| Identifier | MLC-T-CHM-007696 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1350 (https://doi.org/10.1351/pac199567081307) |
| See also | Mesoionic compounds |
Record as JSON
{
"id": "MLC-T-CHM-007696",
"term": "Munchnones",
"field": "Chemistry",
"definition": "A class of five-membered mesoionic heterocyclic compounds, formally known as 1,3-oxazolium-5-olates. Their structure cannot be represented by a single covalent Lewis formula and is instead depicted as a resonance hybrid of several canonical forms, showing delocalized positive and negative charges. Munchnones are highly reactive and are commonly used as 1,3-dipoles in cycloaddition reactions to synthesize other heterocyclic systems, such as pyrroles.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"mesoionic compounds"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1350 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/munchnones/"
}
Record 8,162 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.