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Narcissistic reaction

Term · Chemistry · MLC-T-CHM-007768

A reaction that converts a molecule into its mirror image, so that the product is the enantiomer of the reactant and coincides with the reactant's reflection without any rotation or translation. Because enantiomers have equal energy, such a reaction is a special case of degenerate rearrangement, and it occurs, for example, in fluxional molecules whose rearrangement interconverts the two enantiomeric forms.

Table 1. Record
IdentifierMLC-T-CHM-007768
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1144 (https://doi.org/10.1351/pac199466051077)
See alsoChemical reaction; Degenerate rearrangement; Enantiomer; Fluxional
Record as JSON
{
  "id": "MLC-T-CHM-007768",
  "term": "Narcissistic reaction",
  "field": "Chemistry",
  "definition": "A reaction that converts a molecule into its mirror image, so that the product is the enantiomer of the reactant and coincides with the reactant's reflection without any rotation or translation. Because enantiomers have equal energy, such a reaction is a special case of degenerate rearrangement, and it occurs, for example, in fluxional molecules whose rearrangement interconverts the two enantiomeric forms.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "chemical reaction",
    "degenerate rearrangement",
    "enantiomer",
    "fluxional"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1144 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/narcissistic-reaction/"
}

Record 8,244 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.