MLchartDataset catalogue

Fluxional

Term · Chemistry · MLC-T-CHM-004545

Describing a molecule or ion that undergoes rapid, reversible intramolecular rearrangements, leading to the interchange of chemically equivalent atoms or groups. These rearrangements occur on a timescale that is fast relative to the experimental observation method, such as nuclear magnetic resonance (NMR) spectroscopy. The dynamic nature results in an averaged spectrum.

Table 1. Record
IdentifierMLC-T-CHM-004545
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1115 (https://doi.org/10.1351/pac199466051077)
See alsoChemical species; Degenerate rearrangement; Ligands; Valence tautomerization
Record as JSON
{
  "id": "MLC-T-CHM-004545",
  "term": "Fluxional",
  "field": "Chemistry",
  "definition": "Describing a molecule or ion that undergoes rapid, reversible intramolecular rearrangements, leading to the interchange of chemically equivalent atoms or groups. These rearrangements occur on a timescale that is fast relative to the experimental observation method, such as nuclear magnetic resonance (NMR) spectroscopy. The dynamic nature results in an averaged spectrum.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "chemical species",
    "degenerate rearrangement",
    "ligands",
    "valence tautomerization"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1115 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/fluxional/"
}

Record 4,821 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.