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Stereochemical non-rigidity

Term · Chemistry · MLC-T-CHM-011368

The property of a molecule or molecular entity that undergoes rapid interconversion between different stereoisomeric forms without bond breaking. This dynamic behavior is often observed at room temperature and can involve conformational changes or fluxional processes. An example is the rapid inversion of pyramidal amines.

Table 1. Record
IdentifierMLC-T-CHM-011368
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1964 (https://doi.org/10.1351/pac199971101919)
See alsoIntramolecular; Isomerization
Record as JSON
{
  "id": "MLC-T-CHM-011368",
  "term": "Stereochemical non-rigidity",
  "field": "Chemistry",
  "definition": "The property of a molecule or molecular entity that undergoes rapid interconversion between different stereoisomeric forms without bond breaking. This dynamic behavior is often observed at room temperature and can involve conformational changes or fluxional processes. An example is the rapid inversion of pyramidal amines.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "intramolecular",
    "isomerization"
  ],
  "references": [
    "PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1964 (https://doi.org/10.1351/pac199971101919)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/stereochemical-non-rigidity/"
}

Record 12,107 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.