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Rydberg state

Term · Chemistry · MLC-T-CHM-010464

An electronically excited state of an atom or molecule in which an electron is promoted to an orbital with a very large principal quantum number. These orbitals resemble those of a hydrogen atom, with the excited electron far from the core. Rydberg states exhibit properties similar to those of highly excited hydrogen atoms, including large orbital radii and small ionization energies.

Table 1. Record
IdentifierMLC-T-CHM-010464
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1961 (https://doi.org/10.1351/pac199971101919)
See alsoRydberg orbital; Electronic state; Valence
Record as JSON
{
  "id": "MLC-T-CHM-010464",
  "term": "Rydberg state",
  "field": "Chemistry",
  "definition": "An electronically excited state of an atom or molecule in which an electron is promoted to an orbital with a very large principal quantum number. These orbitals resemble those of a hydrogen atom, with the excited electron far from the core. Rydberg states exhibit properties similar to those of highly excited hydrogen atoms, including large orbital radii and small ionization energies.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Rydberg orbital",
    "electronic state",
    "valence"
  ],
  "references": [
    "PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1961 (https://doi.org/10.1351/pac199971101919)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/rydberg-state/"
}

Record 11,129 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.