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Saytzeff rule

Term · Chemistry · MLC-T-CHM-010536

A rule in organic chemistry that predicts the major product of an elimination reaction, specifically dehydrohalogenation or dehydration. It states that the alkene formed in the greatest amount is the one with the most highly substituted double bond, meaning the one with the most alkyl groups attached to the sp2 carbons. This is often referred to as the 'Zaitsev product'.

Table 1. Record
IdentifierMLC-T-CHM-010536
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
SynonymsZaitsev rule
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1162 (https://doi.org/10.1351/pac199466051077)
See alsoHofmann rule; Markownikoff rule; Elimination; Olefins; Stable
Record as JSON
{
  "id": "MLC-T-CHM-010536",
  "term": "Saytzeff rule",
  "field": "Chemistry",
  "definition": "A rule in organic chemistry that predicts the major product of an elimination reaction, specifically dehydrohalogenation or dehydration. It states that the alkene formed in the greatest amount is the one with the most highly substituted double bond, meaning the one with the most alkyl groups attached to the sp2 carbons. This is often referred to as the 'Zaitsev product'.",
  "synonyms": [
    "Zaitsev rule"
  ],
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Hofmann rule",
    "Markownikoff rule",
    "elimination",
    "olefins",
    "stable"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1162 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/saytzeff-rule/"
}

Record 11,207 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.