Structure
Term · Chemistry · MLC-T-CHM-013600
The spatial arrangement of atoms or ions within a solid catalyst, particularly at its surface. This arrangement determines the geometry and availability of active sites where catalytic reactions occur. Reactions are classified as structure-sensitive if their rate depends on the specific crystal faces or surface defects exposed, whereas structure-insensitive reactions proceed at similar rates regardless of the surface topography.
| Identifier | MLC-T-CHM-013600 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| References | PAC, 1976, 46, 71. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis' on page 79 (https://doi.org/10.1351/pac197646010071) |
| See also | Catalyst |
Record as JSON
{
"id": "MLC-T-CHM-013600",
"term": "Structure",
"field": "Chemistry",
"definition": "The spatial arrangement of atoms or ions within a solid catalyst, particularly at its surface. This arrangement determines the geometry and availability of active sites where catalytic reactions occur. Reactions are classified as structure-sensitive if their rate depends on the specific crystal faces or surface defects exposed, whereas structure-insensitive reactions proceed at similar rates regardless of the surface topography.",
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"catalyst"
],
"references": [
"PAC, 1976, 46, 71. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis' on page 79 (https://doi.org/10.1351/pac197646010071)"
],
"url": "https://mlchart.com/terminology/chemistry/structure/"
}
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