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TICT state

Term · Chemistry · MLC-T-CHM-012056

A twisted intramolecular charge transfer state, formed when a molecule undergoes a substantial change in its geometry upon excitation, leading to a separation of charge. This state often involves a large dihedral angle between donor and acceptor moieties within the same molecule. TICT states are characterized by a large Stokes shift in their fluorescence emission compared to the locally excited state.

Table 1. Record
IdentifierMLC-T-CHM-012056
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2280 (https://doi.org/10.1351/pac199668122223)
See alsoStokes; Fluorescence; Twisted intramolecular charge transfer
Record as JSON
{
  "id": "MLC-T-CHM-012056",
  "term": "TICT state",
  "field": "Chemistry",
  "definition": "A twisted intramolecular charge transfer state, formed when a molecule undergoes a substantial change in its geometry upon excitation, leading to a separation of charge. This state often involves a large dihedral angle between donor and acceptor moieties within the same molecule. TICT states are characterized by a large Stokes shift in their fluorescence emission compared to the locally excited state.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "stokes",
    "fluorescence",
    "twisted intramolecular charge transfer"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2280 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/tict-state/"
}

Record 12,859 of 13,678 in Chemistry terminology (MLC-0109). Request the full dataset.