MLchartDataset catalogue

Tolyl ion

Term · Chemistry · MLC-T-CHM-012102

A carbocation with the chemical formula C7H7+, derived from toluene by the formal removal of a hydride ion. This ion exists as three structural isomers: ortho-tolyl, meta-tolyl, and para-tolyl, corresponding to the position of the positive charge on the benzene ring relative to the methyl group. The tolyl ion is a distinct species from the more stable tropylium ion, which is a common fragment in the mass spectra of toluene and related compounds.

Table 1. Record
IdentifierMLC-T-CHM-012102
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1596 (https://doi.org/10.1351/PAC-REC-06-04-06)
See alsoBenzyl ion
Record as JSON
{
  "id": "MLC-T-CHM-012102",
  "term": "Tolyl ion",
  "field": "Chemistry",
  "definition": "A carbocation with the chemical formula C7H7+, derived from toluene by the formal removal of a hydride ion. This ion exists as three structural isomers: ortho-tolyl, meta-tolyl, and para-tolyl, corresponding to the position of the positive charge on the benzene ring relative to the methyl group. The tolyl ion is a distinct species from the more stable tropylium ion, which is a common fragment in the mass spectra of toluene and related compounds.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "benzyl ion"
  ],
  "references": [
    "PAC, 2013, 85, 1515. 'Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)' on page 1596 (https://doi.org/10.1351/PAC-REC-06-04-06)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/tolyl-ion/"
}

Record 12,907 of 13,678 in Chemistry terminology (MLC-0109). Request the full dataset.