Activity coefficient
Term · Chemistry · MLC-T-CHM-000197
A dimensionless factor that relates the activity of a chemical species to its concentration in a solution, quantifying the deviation from ideal behavior. It accounts for the non-ideal interactions between molecules in a real solution, which affect the chemical potential. For an ideal solution, the activity coefficient is equal to one.
| Identifier | MLC-T-CHM-000197 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| References | PAC, 1990, 62, 2167. 'Glossary of atmospheric chemistry terms (Recommendations 1990)' on page 2171 (https://doi.org/10.1351/pac199062112167); PAC, 1994, 66, 533. 'Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)' on page 543 (https://doi.org/10.1351/pac199466030533); PAC, 1996, 68, 957. 'Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)' on page 960 (https://doi.org/10.1351/pac199668040957) |
| See also | Chemical potential; Coefficient; Mole |
Record as JSON
{
"id": "MLC-T-CHM-000197",
"term": "Activity coefficient",
"field": "Chemistry",
"definition": "A dimensionless factor that relates the activity of a chemical species to its concentration in a solution, quantifying the deviation from ideal behavior. It accounts for the non-ideal interactions between molecules in a real solution, which affect the chemical potential. For an ideal solution, the activity coefficient is equal to one.",
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"chemical potential",
"coefficient",
"mole"
],
"references": [
"PAC, 1990, 62, 2167. 'Glossary of atmospheric chemistry terms (Recommendations 1990)' on page 2171 (https://doi.org/10.1351/pac199062112167)",
"PAC, 1994, 66, 533. 'Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)' on page 543 (https://doi.org/10.1351/pac199466030533)",
"PAC, 1996, 68, 957. 'Glossary of terms in quantities and units in Clinical Chemistry (IUPAC-IFCC Recommendations 1996)' on page 960 (https://doi.org/10.1351/pac199668040957)"
],
"url": "https://mlchart.com/terminology/chemistry/activity-coefficient/"
}
Record 204 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.