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Osmotic coefficient

Term · Chemistry · MLC-T-CHM-008351

A dimensionless quantity that measures the deviation of the colligative properties of a real solution from those of an ideal solution, particularly related to osmotic pressure and vapor pressure lowering. It accounts for the non-ideal behavior of solutes due to intermolecular interactions. For an ideal solution, the osmotic coefficient is equal to one.

Table 1. Record
IdentifierMLC-T-CHM-008351
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesGreen Book, 2nd ed., p. 51 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf); PAC, 1994, 66, 533. 'Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)' on page 546 (https://doi.org/10.1351/pac199466030533)
See alsoHenry's law; Coefficient; Deviation; Gas constant; Solution
Record as JSON
{
  "id": "MLC-T-CHM-008351",
  "term": "Osmotic coefficient",
  "field": "Chemistry",
  "definition": "A dimensionless quantity that measures the deviation of the colligative properties of a real solution from those of an ideal solution, particularly related to osmotic pressure and vapor pressure lowering. It accounts for the non-ideal behavior of solutes due to intermolecular interactions. For an ideal solution, the osmotic coefficient is equal to one.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "Henry's law",
    "coefficient",
    "deviation",
    "gas constant",
    "solution"
  ],
  "references": [
    "Green Book, 2nd ed., p. 51 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf)",
    "PAC, 1994, 66, 533. 'Standard quantities in chemical thermodynamics. Fugacities, activities and equilibrium constants for pure and mixed phases (IUPAC Recommendations 1994)' on page 546 (https://doi.org/10.1351/pac199466030533)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/osmotic-coefficient/"
}

Record 8,874 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.