Esin and Markov coefficient

{
  "id": "MLC-T-CHM-004098",
  "term": "Esin and Markov coefficient",
  "field": "Chemistry",
  "definition": "A coefficient that quantifies the dependence of the potential difference across an interface on the chemical potential of an adsorbed species. This coefficient is particularly relevant in electrochemistry for understanding the adsorption behavior of ions at electrode surfaces. It relates changes in electrode potential to changes in the activity of specific ions in solution.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "Gibbs adsorption",
    "charge density",
    "chemical potential",
    "surface excess",
    "variable"
  ],
  "references": [
    "PAC, 1986, 58, 437. 'Interphases in systems of conducting phases (Recommendations 1985)' on page 446 (https://doi.org/10.1351/pac198658030437)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/esin-and-markov-coefficient/"
}