Attenuated total reflection
Term · Chemistry · MLC-T-CHM-000929
A phenomenon where an electromagnetic wave, typically infrared light, undergoes total internal reflection at the interface between a high refractive index crystal and a lower refractive index sample. A portion of the evanescent wave penetrates into the sample, allowing for absorption of energy. This technique is widely used in infrared spectroscopy for analyzing opaque or highly absorbing samples.
| Identifier | MLC-T-CHM-000929 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| Synonyms | frustrated total internal reflection |
| References | PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 652 (https://doi.org/10.1515/pac-2019-0203) |
| See also | Internal reflection; Angle of incidence; Attenuated total reflection spectroscopy; Critical angle; Multiple attenuated total reflection |
Record as JSON
{
"id": "MLC-T-CHM-000929",
"term": "Attenuated total reflection",
"field": "Chemistry",
"definition": "A phenomenon where an electromagnetic wave, typically infrared light, undergoes total internal reflection at the interface between a high refractive index crystal and a lower refractive index sample. A portion of the evanescent wave penetrates into the sample, allowing for absorption of energy. This technique is widely used in infrared spectroscopy for analyzing opaque or highly absorbing samples.",
"synonyms": [
"frustrated total internal reflection"
],
"subject": "Analytical Chemistry",
"see_also": [
"internal reflection",
"angle of incidence",
"attenuated total reflection spectroscopy",
"critical angle",
"multiple attenuated total reflection"
],
"references": [
"PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 652 (https://doi.org/10.1515/pac-2019-0203)"
],
"url": "https://mlchart.com/terminology/chemistry/attenuated-total-reflection/"
}
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