Borderline mechanism
Term · Chemistry · MLC-T-CHM-001438
A reaction mechanism that does not fit neatly into a purely dissociative or purely associative pathway, exhibiting characteristics of both. This often occurs when the transition state involves partial bond breaking and partial bond formation simultaneously. Such mechanisms are common in nucleophilic substitution reactions at saturated carbon.
| Identifier | MLC-T-CHM-001438 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1090 (https://doi.org/10.1351/pac199466051077) |
| See also | Electron transfer |
Record as JSON
{
"id": "MLC-T-CHM-001438",
"term": "Borderline mechanism",
"field": "Chemistry",
"definition": "A reaction mechanism that does not fit neatly into a purely dissociative or purely associative pathway, exhibiting characteristics of both. This often occurs when the transition state involves partial bond breaking and partial bond formation simultaneously. Such mechanisms are common in nucleophilic substitution reactions at saturated carbon.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"electron transfer"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1090 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/borderline-mechanism/"
}
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