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Donor number

Term · Chemistry · MLC-T-CHM-003384

An empirical parameter that quantifies the Lewis basicity or electron-donating ability of a solvent. It is defined as the negative enthalpy of reaction for the formation of a 1:1 adduct between the solvent and antimony pentachloride (SbCl5) in dilute 1,2-dichloroethane solution. Higher donor numbers indicate stronger Lewis bases.

Table 1. Record
IdentifierMLC-T-CHM-003384
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1107 (https://doi.org/10.1351/pac199466051077)
See alsoLewis basicity
Record as JSON
{
  "id": "MLC-T-CHM-003384",
  "term": "Donor number",
  "field": "Chemistry",
  "definition": "An empirical parameter that quantifies the Lewis basicity or electron-donating ability of a solvent. It is defined as the negative enthalpy of reaction for the formation of a 1:1 adduct between the solvent and antimony pentachloride (SbCl5) in dilute 1,2-dichloroethane solution. Higher donor numbers indicate stronger Lewis bases.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Lewis basicity"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1107 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/donor-number/"
}

Record 3,596 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.