Globally optimized alternating-phase rectangular pulses
Term · Chemistry · MLC-T-CHM-013127
A sequence of radiofrequency pulses used in nuclear magnetic resonance (NMR) spectroscopy, designed to achieve efficient and broadband spin decoupling. These pulses employ alternating phases and rectangular shapes, optimized across a range of frequencies. They are particularly effective in suppressing unwanted couplings in complex NMR spectra.
| Identifier | MLC-T-CHM-013127 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| References | PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 688 (https://doi.org/10.1515/pac-2019-0203) |
| See also | Spin decoupling; Nuclear magnetic resonance spectrum; Nuclear magnetic resonance spectroscopy |
Record as JSON
{
"id": "MLC-T-CHM-013127",
"term": "Globally optimized alternating-phase rectangular pulses",
"field": "Chemistry",
"definition": "A sequence of radiofrequency pulses used in nuclear magnetic resonance (NMR) spectroscopy, designed to achieve efficient and broadband spin decoupling. These pulses employ alternating phases and rectangular shapes, optimized across a range of frequencies. They are particularly effective in suppressing unwanted couplings in complex NMR spectra.",
"subject": "Analytical Chemistry",
"see_also": [
"spin decoupling",
"nuclear magnetic resonance spectrum",
"nuclear magnetic resonance spectroscopy"
],
"references": [
"PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 688 (https://doi.org/10.1515/pac-2019-0203)"
],
"url": "https://mlchart.com/terminology/chemistry/globally-optimized-alternating-phase-rectangular-pulses/"
}
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