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Inner filter effect

Term · Chemistry · MLC-T-CHM-005881

The attenuation of incident or emitted light in a spectroscopic experiment due to absorption by the sample itself or other components in the solution. This phenomenon can lead to a non-linear relationship between analyte concentration and measured signal intensity. It is particularly relevant in fluorescence spectroscopy, where both excitation and emission light can be absorbed.

Table 1. Record
IdentifierMLC-T-CHM-005881
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2247 (https://doi.org/10.1351/pac199668122223)
See alsoAbsorber; Irradiation; Quantum yield
Record as JSON
{
  "id": "MLC-T-CHM-005881",
  "term": "Inner filter effect",
  "field": "Chemistry",
  "definition": "The attenuation of incident or emitted light in a spectroscopic experiment due to absorption by the sample itself or other components in the solution. This phenomenon can lead to a non-linear relationship between analyte concentration and measured signal intensity. It is particularly relevant in fluorescence spectroscopy, where both excitation and emission light can be absorbed.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "absorber",
    "irradiation",
    "quantum yield"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2247 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/inner-filter-effect/"
}

Record 6,236 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.