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Isomorphous structures

Term · Chemistry · MLC-T-CHM-006209

Chains in a polymer crystal that have identical chirality and conformation, such as two helices of isotactic polypropylene with the same screw sense. Neighbouring chains that match in conformation but are mirror images are enantiomorphous instead, like right-handed and left-handed helices. Chains of either kind may also differ in orientation along the axis, which the terms isoclined and anticlined describe.

Table 1. Record
IdentifierMLC-T-CHM-006209
FieldChemistry
SubjectPolymer
ReferencesPurple Book, 1st ed., p. 43 (http://old.iupac.org/publications/books/author/metanomski.html)
See alsoChirality; Conformation; Pendant group
Record as JSON
{
  "id": "MLC-T-CHM-006209",
  "term": "Isomorphous structures",
  "field": "Chemistry",
  "definition": "Chains in a polymer crystal that have identical chirality and conformation, such as two helices of isotactic polypropylene with the same screw sense. Neighbouring chains that match in conformation but are mirror images are enantiomorphous instead, like right-handed and left-handed helices. Chains of either kind may also differ in orientation along the axis, which the terms isoclined and anticlined describe.",
  "subject": "Polymer",
  "see_also": [
    "chirality",
    "conformation",
    "pendant group"
  ],
  "references": [
    "Purple Book, 1st ed., p. 43 (http://old.iupac.org/publications/books/author/metanomski.html)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/isomorphous-structures/"
}

Record 6,591 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.