MLchartDataset catalogue

Living coordination polymerization

Term · Chemistry · MLC-T-CHM-006716

A coordination polymerization process where the active centers remain viable throughout the reaction, and chain transfer and termination are negligible. This allows for precise control over polymer molecular weight, polydispersity, and architecture. It is often achieved using specific transition metal catalysts, such as Ziegler-Natta catalysts under controlled conditions.

Table 1. Record
IdentifierMLC-T-CHM-006716
FieldChemistry
SubjectPolymer
ReferencesPAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1136 (https://doi.org/10.1515/pac-2020-1211)
See alsoCoordination polymerization; Chain termination; Reversible-deactivation coordination polymerization
Record as JSON
{
  "id": "MLC-T-CHM-006716",
  "term": "Living coordination polymerization",
  "field": "Chemistry",
  "definition": "A coordination polymerization process where the active centers remain viable throughout the reaction, and chain transfer and termination are negligible. This allows for precise control over polymer molecular weight, polydispersity, and architecture. It is often achieved using specific transition metal catalysts, such as Ziegler-Natta catalysts under controlled conditions.",
  "subject": "Polymer",
  "see_also": [
    "coordination polymerization",
    "chain termination",
    "reversible-deactivation coordination polymerization"
  ],
  "references": [
    "PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1136 (https://doi.org/10.1515/pac-2020-1211)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/living-coordination-polymerization/"
}

Record 7,115 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.