Nernstian response
Term · Chemistry · MLC-T-CHM-007828
The behavior of an ion-selective electrode or electrochemical cell where the electrode potential changes linearly with the logarithm of the activity of the target ion, with a slope close to the theoretical Nernst slope. This ideal response indicates that the electrode is functioning correctly and selectively. For a monovalent ion at 25 °C, the Nernstian slope is approximately 59.16 mV per decade change in activity.
| Identifier | MLC-T-CHM-007828 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| References | PAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 665 (https://doi.org/10.1515/pac-2018-0109) |
| See also | Nernst equation; Electron number of an electrochemical reaction |
Record as JSON
{
"id": "MLC-T-CHM-007828",
"term": "Nernstian response",
"field": "Chemistry",
"definition": "The behavior of an ion-selective electrode or electrochemical cell where the electrode potential changes linearly with the logarithm of the activity of the target ion, with a slope close to the theoretical Nernst slope. This ideal response indicates that the electrode is functioning correctly and selectively. For a monovalent ion at 25 °C, the Nernstian slope is approximately 59.16 mV per decade change in activity.",
"subject": "Analytical Chemistry",
"see_also": [
"Nernst equation",
"electron number of an electrochemical reaction"
],
"references": [
"PAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 665 (https://doi.org/10.1515/pac-2018-0109)"
],
"url": "https://mlchart.com/terminology/chemistry/nernstian-response/"
}
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