Pauli exclusion principle
Term · Chemistry · MLC-T-CHM-008555
A quantum mechanical principle asserting that no two identical fermions, such as electrons, can occupy the same quantum state simultaneously within a single quantum system. For electrons in an atom, this implies that no two electrons can have the same set of four quantum numbers: the principal quantum number (n), the azimuthal quantum number (l), the magnetic quantum number (ml), and the spin quantum number (ms). Consequently, any single atomic orbital can accommodate a maximum of two electrons, which must have opposite spins.
| Identifier | MLC-T-CHM-008555 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1956 (https://doi.org/10.1351/pac199971101919) |
| See also | Antisymmetry principle; Asymmetric; Aufbau principle; Configuration |
Record as JSON
{
"id": "MLC-T-CHM-008555",
"term": "Pauli exclusion principle",
"field": "Chemistry",
"definition": "A quantum mechanical principle asserting that no two identical fermions, such as electrons, can occupy the same quantum state simultaneously within a single quantum system. For electrons in an atom, this implies that no two electrons can have the same set of four quantum numbers: the principal quantum number (n), the azimuthal quantum number (l), the magnetic quantum number (ml), and the spin quantum number (ms). Consequently, any single atomic orbital can accommodate a maximum of two electrons, which must have opposite spins.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"antisymmetry principle",
"asymmetric",
"aufbau principle",
"configuration"
],
"references": [
"PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1956 (https://doi.org/10.1351/pac199971101919)"
],
"url": "https://mlchart.com/terminology/chemistry/pauli-exclusion-principle/"
}
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