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Photorearrangement

Term · Chemistry · MLC-T-CHM-008916

A chemical reaction in which the atoms within a molecule rearrange their connectivity following the absorption of light. This process leads to the formation of an isomer of the starting material, often involving the migration of groups or changes in ring structure. Examples include the di-π-methane rearrangement and photoisomerization reactions.

Table 1. Record
IdentifierMLC-T-CHM-008916
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 398 (https://doi.org/10.1351/pac200779030293)
See alsoAlkenes; Di-π-methane rearrangement; Photoisomerization; Cis, trans; Unstable
Record as JSON
{
  "id": "MLC-T-CHM-008916",
  "term": "Photorearrangement",
  "field": "Chemistry",
  "definition": "A chemical reaction in which the atoms within a molecule rearrange their connectivity following the absorption of light. This process leads to the formation of an isomer of the starting material, often involving the migration of groups or changes in ring structure. Examples include the di-π-methane rearrangement and photoisomerization reactions.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "alkenes",
    "di-π-methane rearrangement",
    "photoisomerization",
    "cis, trans",
    "unstable"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 398 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/photorearrangement/"
}

Record 9,470 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.