Specific catalysis
Term · Chemistry · MLC-T-CHM-011100
A type of catalysis where the reaction rate is directly proportional to the concentration of a specific acid or base species, such as H3O+ or OH-, and is independent of the concentration of other acidic or basic species present. This occurs when the proton transfer step is rapid and reversible, and the rate-determining step involves the protonated or deprotonated form of the reactant. It is distinct from general acid-base catalysis.
| Identifier | MLC-T-CHM-011100 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1165 (https://doi.org/10.1351/pac199466051077) |
| See also | Acceleration; Catalysis; Catalyst; General acid catalysis; General base catalysis; Lyate ion; Lyonium ion; Pseudo-catalysis |
Record as JSON
{
"id": "MLC-T-CHM-011100",
"term": "Specific catalysis",
"field": "Chemistry",
"definition": "A type of catalysis where the reaction rate is directly proportional to the concentration of a specific acid or base species, such as H3O+ or OH-, and is independent of the concentration of other acidic or basic species present. This occurs when the proton transfer step is rapid and reversible, and the rate-determining step involves the protonated or deprotonated form of the reactant. It is distinct from general acid-base catalysis.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"acceleration",
"catalysis",
"catalyst",
"general acid catalysis",
"general base catalysis",
"lyate ion",
"lyonium ion",
"pseudo-catalysis"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1165 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/specific-catalysis/"
}
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