Debye-Hückel equation
Term · Chemistry · MLC-T-CHM-002888
A mathematical expression used to calculate the activity coefficient of an ion in a dilute electrolyte solution. The equation models how the electrostatic interactions between ions in a solution cause their behavior to deviate from that of an ideal solution. The limiting law form of the equation is valid only for very low ionic strengths, typically below 0.01 mol/kg, while extended versions apply to slightly more concentrated solutions.
| Identifier | MLC-T-CHM-002888 |
|---|---|
| Field | Chemistry |
| Subject | Chemistry and Human Health |
| References | PAC, 1984, 56, 567. 'Physicochemical quantities and units in clinical chemistry with special emphasis on activities and activity coefficients (Recommendations 1983)' on page 569 (https://doi.org/10.1351/pac198456050567) |
| See also | Debye; Charge number; Chemical potential; Coefficient; Electrochemical potential; Ionic strength; pH |
Record as JSON
{
"id": "MLC-T-CHM-002888",
"term": "Debye-Hückel equation",
"field": "Chemistry",
"definition": "A mathematical expression used to calculate the activity coefficient of an ion in a dilute electrolyte solution. The equation models how the electrostatic interactions between ions in a solution cause their behavior to deviate from that of an ideal solution. The limiting law form of the equation is valid only for very low ionic strengths, typically below 0.01 mol/kg, while extended versions apply to slightly more concentrated solutions.",
"subject": "Chemistry and Human Health",
"see_also": [
"debye",
"charge number",
"chemical potential",
"coefficient",
"electrochemical potential",
"ionic strength",
"pH"
],
"references": [
"PAC, 1984, 56, 567. 'Physicochemical quantities and units in clinical chemistry with special emphasis on activities and activity coefficients (Recommendations 1983)' on page 569 (https://doi.org/10.1351/pac198456050567)"
],
"url": "https://mlchart.com/terminology/chemistry/debye-huckel-equation/"
}
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