Diastereotopic
Term · Chemistry · MLC-T-CHM-003140
Describing two identical groups or faces in a molecule that, if replaced or reacted, would lead to diastereoisomers. These groups or faces are chemically non-equivalent and can be distinguished by spectroscopic methods, such as nuclear magnetic resonance (NMR) spectroscopy. For example, the two protons on a methylene group adjacent to a chiral center are diastereotopic.
| Identifier | MLC-T-CHM-003140 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2206 (https://doi.org/10.1351/pac199668122193) |
| See also | Diastereoisomerism; Enantiotopic; Prochirality |
Record as JSON
{
"id": "MLC-T-CHM-003140",
"term": "Diastereotopic",
"field": "Chemistry",
"definition": "Describing two identical groups or faces in a molecule that, if replaced or reacted, would lead to diastereoisomers. These groups or faces are chemically non-equivalent and can be distinguished by spectroscopic methods, such as nuclear magnetic resonance (NMR) spectroscopy. For example, the two protons on a methylene group adjacent to a chiral center are diastereotopic.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"diastereoisomerism",
"enantiotopic",
"prochirality"
],
"references": [
"PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2206 (https://doi.org/10.1351/pac199668122193)"
],
"url": "https://mlchart.com/terminology/chemistry/diastereotopic/"
}
Record 3,343 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.