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Superacid

Term · Chemistry · MLC-T-CHM-011586

An acidic medium with a proton-donating ability greater than that of pure sulfuric acid. Its acidity is quantified by the Hammett acidity function (H₀), with superacids having H₀ values more negative than −12, the value for 100% H₂SO₄. A common example is "magic acid", a mixture of antimony pentafluoride and fluorosulfuric acid, which is strong enough to protonate alkanes.

Table 1. Record
IdentifierMLC-T-CHM-011586
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1169 (https://doi.org/10.1351/pac199466051077)
See alsoBrønsted acid; Lewis acid; Acidity; Basicity; Catalysis
Record as JSON
{
  "id": "MLC-T-CHM-011586",
  "term": "Superacid",
  "field": "Chemistry",
  "definition": "An acidic medium with a proton-donating ability greater than that of pure sulfuric acid. Its acidity is quantified by the Hammett acidity function (H₀), with superacids having H₀ values more negative than −12, the value for 100% H₂SO₄. A common example is \"magic acid\", a mixture of antimony pentafluoride and fluorosulfuric acid, which is strong enough to protonate alkanes.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Brønsted acid",
    "Lewis acid",
    "acidity",
    "basicity",
    "catalysis"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1169 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/superacid/"
}

Record 12,346 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.