MLchartDataset catalogue

Synchronous

Term · Chemistry · MLC-T-CHM-011748

A concerted process whose bond formation and bond rupture are equally advanced when the transition state is reached, so that neither lags behind the other. A concerted reaction can instead be asynchronous, with one bond change well ahead of the other, as in many Diels-Alder reactions of unsymmetrical partners. The cycloaddition of butadiene with ethylene is the textbook example, with both new sigma bonds forming to the same extent.

Table 1. Record
IdentifierMLC-T-CHM-011748
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1170 (https://doi.org/10.1351/pac199466051077)
See alsoConcerted process; Imbalance; Primitive change; Transition state
Record as JSON
{
  "id": "MLC-T-CHM-011748",
  "term": "Synchronous",
  "field": "Chemistry",
  "definition": "A concerted process whose bond formation and bond rupture are equally advanced when the transition state is reached, so that neither lags behind the other. A concerted reaction can instead be asynchronous, with one bond change well ahead of the other, as in many Diels-Alder reactions of unsymmetrical partners. The cycloaddition of butadiene with ethylene is the textbook example, with both new sigma bonds forming to the same extent.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "concerted process",
    "imbalance",
    "primitive change",
    "transition state"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1170 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/synchronous/"
}

Record 12,522 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.