MLchartDataset catalogue

Koppel-Palm solvent parameters

Term · Chemistry · MLC-T-CHM-006379

A four-term set of empirical solvent parameters describing solvation through polarity Y, derived from the dielectric constant, polarizability P, derived from the refractive index, and electrophilicity E and basicity B, the last two taken from spectral shifts of probe molecules. They are combined in a multiparameter linear free energy equation to correlate solvent effects on rates and equilibrium constants.

Table 1. Record
IdentifierMLC-T-CHM-006379
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1134 (https://doi.org/10.1351/pac199466051077)
See alsoAcidity; Basicity; Electrophilicity; Nucleophilicity; Permittivity; Polarity; Refractive index
Record as JSON
{
  "id": "MLC-T-CHM-006379",
  "term": "Koppel-Palm solvent parameters",
  "field": "Chemistry",
  "definition": "A four-term set of empirical solvent parameters describing solvation through polarity Y, derived from the dielectric constant, polarizability P, derived from the refractive index, and electrophilicity E and basicity B, the last two taken from spectral shifts of probe molecules. They are combined in a multiparameter linear free energy equation to correlate solvent effects on rates and equilibrium constants.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "acidity",
    "basicity",
    "electrophilicity",
    "nucleophilicity",
    "permittivity",
    "polarity",
    "refractive index"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1134 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/koppel-palm-solvent-parameters/"
}

Record 6,769 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.